Lower rim-modified calix[4]arenes with fragments of EDTA (DTPA) and their Ln(III) complexes (Ln = Yb, Lu): synthesis and NIR-luminescent properties
Vol. 86 No. 5 (2020), Inorganic Chemistry
Vol. 86 No. 5 (2020)

Lower rim-modified calix[4]arenes with fragments of EDTA (DTPA) and their Ln(III) complexes (Ln = Yb, Lu): synthesis and NIR-luminescent properties

Inorganic Chemistry
https://doi.org/10.33609/2708-129X.86.5.2020.13-23
Published July 15, 2020
Serhii Smola
A.V. Bogatsky Physico-Chemical Institute of the NAS of Ukraine
https://orcid.org/0000-0002-4121-3382
Yevhen Fadieiev
A.V. Bogatsky Physico-Chemical Institute of the NAS of Ukraine
https://orcid.org/0000-0003-2181-1999
Mariia Rusakova
I.I. Mechnikov Odessa National University
Olga Snurnikova
A.V. Bogatsky Physico-Chemical Institute of the NAS of Ukraine
https://orcid.org/0000-0002-8631-9316
Olena Alyeksyeyeva
A.V. Bogatsky Physico-Chemical Institute of the NAS of Ukraine
Nataliya Rusakova
A.V. Bogatsky Physico-Chemical Institute of the NAS of Ukraine
https://orcid.org/0000-0001-9349-9995
№2

Keywords

calix[4]arenes, EDTA, DTPA, lanthanides, luminescence.

How to Cite

Smola, S., Fadieiev, Y., Rusakova, M., Snurnikova, O., Alyeksyeyeva, O., & Rusakova, N. (2020). Lower rim-modified calix[4]arenes with fragments of EDTA (DTPA) and their Ln(III) complexes (Ln = Yb, Lu): synthesis and NIR-luminescent properties. Ukrainian Chemistry Journal, 86(5), 13-23. https://doi.org/10.33609/2708-129X.86.5.2020.13-23
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Abstract

Derivatives of p-tert-butylcalix[4]arene substituted on the lower rim with fragments of aminopolycarboxylic acids (EDTA, DTPA) were obtained. Mono and binuclear complexes with lanthanide (III) ions were synthesized using these compounds. The effect of the number and type of aminopolycarboxylic acid fragments on the luminescence of ligands and complexes was studied. The influence of the distance between the emitting ion and the calixarene macrocycle on the intensity of 4f-luminescence was analyzed.

https://doi.org/10.33609/2708-129X.86.5.2020.13-23
№2

References

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