Анотація
Derivatives of p-tert-butylcalix[4]arene substituted on the lower rim with fragments of aminopolycarboxylic acids (EDTA, DTPA) were obtained. Mono and binuclear complexes with lanthanide (III) ions were synthesized using these compounds. The effect of the number and type of aminopolycarboxylic acid fragments on the luminescence of ligands and complexes was studied. The influence of the distance between the emitting ion and the calixarene macrocycle on the intensity of 4f-luminescence was analyzed.
Посилання
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4. Alyeksyeyeva O.A., Lukyanenko A.P., Shneider N.V., Golovenko M.Ya. The syn-thesis of p-tert-butylcalix[4]arene with 14C-acetic acid residues. Ukrainica Bioorganica Acta. 2009. 1: 28.
5. Lin Y., Leydier A., Métay E., Favre-Réguillon A., Bouchu D., Pellet-Rostaing S., Lemaire M. Synthesis of original capping calixarenes with DTPA fragment. J. Incl. Phenom. Macrocycl. Chem. 2008. 61: 187.
6. Fadeyev Ye.M., Snurnikova O.V., Lukyanenko O.P., Alyeksyeyeva O.O., Rusakova N.V. Synthesis and spectral-luminescent properties of calix[4]arenes modified with carboxylic, phthalimide and aminoethoxy-groups, and their lanthanide-containing complexes. Visnyk ONU. Ser. Chemistry. 2011. 16: 18.
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2. Chemistry of guest-host complexes: synthesis, structures and applications. Eds. F. Vogtle, E. Weber (Moscow, Mir, 1988).
3. Girek T., Sliwa W. Calixarene complexes with metal ions. J. Incl. Phenom. Macrocycl. Chem. 2010. 66: 15.
4. Alyeksyeyeva O.A., Lukyanenko A.P., Shneider N.V., Golovenko M.Ya. The syn-thesis of p-tert-butylcalix[4]arene with 14C-acetic acid residues. Ukrainica Bioorganica Acta. 2009. 1: 28.
5. Lin Y., Leydier A., Métay E., Favre-Réguillon A., Bouchu D., Pellet-Rostaing S., Lemaire M. Synthesis of original capping calixarenes with DTPA fragment. J. Incl. Phenom. Macrocycl. Chem. 2008. 61: 187.
6. Fadeyev Ye.M., Snurnikova O.V., Lukyanenko O.P., Alyeksyeyeva O.O., Rusakova N.V. Synthesis and spectral-luminescent properties of calix[4]arenes modified with carboxylic, phthalimide and aminoethoxy-groups, and their lanthanide-containing complexes. Visnyk ONU. Ser. Chemistry. 2011. 16: 18.
7. Coordination chemistry of rare earth elements. Eds. V.I. Spitsyn, L.I. Martynenko (Moscow, MSU, 1979).
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Авторське право (c) 2020 Serhii Smola, Yevhen Fadieiev, Mariia Rusakova, Olga Snurnikova, Olena Alyeksyeyeva, Nataliya Rusakova
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