ELECTROCHEMICAL CHARACTERISTICS OF TIN FILMS IN CYCLING IN LITHIUM-ION BATTERIES
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Keywords

electrodeposition, pyrophosphate electrolyte, tin films, specific capacity, reversibility, lithium-ion battery.

How to Cite

Shmatok, Y., Globa, N., Nikitenko, V., Babenkov, E., & Kublanovsky, V. (2019). ELECTROCHEMICAL CHARACTERISTICS OF TIN FILMS IN CYCLING IN LITHIUM-ION BATTERIES. Ukrainian Chemistry Journal, 85(10), 67-77. https://doi.org/10.33609/0041-6045.85.10.2019.67-77

Abstract

Thin electrolytic fine tin sediments were obtained from pyrophosphate electrolyte under different electrolysis conditions and duration. The electrochemical characteristics of tin coatings as anode materials of lithium-ion batteries are studied using potentiodynamic and galvanostatic cycling methods. The effect of the properties of coatings, in particular their mass, on the value of specific capacitance and its stability, including during discharge with different current densities, has been established. It is shown that the studied tin sediments have high initial specific capacity that is close to theoretically possible. The maximum stability of the specific capacity during cycling is characteristic of electrodes with minimal masses of precipitation. The impedance spectra recorded for the studied electrodes in the initial state and after the first lithiation are analyzed.

https://doi.org/10.33609/0041-6045.85.10.2019.67-77
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