coordination compounds, rare earth elements, d-metals, platinum metals, ligands.

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The review considers the main stages of development of the chemistry of coordination compounds at the Institute of General and Inorganic Chemistry. VI Vernadsky National Academy of Sciences of Ukraine on the occasion of the 90th anniversary of its founding. An overview of complex compounds of p, d, f-me­tals with different classes of ligands (inorganic and organic), features of their synthesis, study of the structure and properties of the obtained compounds, contains current material on the use of synthesized complexes to create functional materials for different purposes. Me­thods of synthesis have been developed, do­zens of new coordination compounds with derivatives of hydrazones, amines, azomethanes, and thiosemicarbazones have been synthesized and isolated in the individual state. Their composition, structure and physicochemical pro­perties are determined. The general regularities that take place in the process of comp­lexation of metals with ligands, as well as factors influencing the composition, structure and physico­chemical properties of the obtained coordination compounds are established.

For the long history of the Institute has accumulated a huge amount of material on the problems of modern coordination chemistry. Significant research in this area belongs to Ukrainian scientists who have worked long and fruitfully at the Institute: A.K. Babko, К.B. Yat­si­mirsky, Ya.A. Fialkov, I.A. Sheka, S.V. Volkov, N.A. Kostromina, and who created scientific schools, known not only in Ukraine but also abroad. To date, the attention of scientists of the Institute has shifted from classical monomeric to bigeteronuclear, polynuclear, multiligand complexes, which is primarily due to intensive research of new functional materials: optical and magnetic, biologically active substances, as well as effective adsorbents, che­mical sensors, catalysts, catalysts, catalysts and biochemical processes.


Kostromina N.A., Kumok V.N., Skorik N.A. Chemistry of coordination compounds. Moscow: Higher school, 1990 [in Russian].

Kostromina N.A., Voloshin Ya.Z., Nazarenko A.Yu. Clathrochelates: synthesis, structure, properties. Кyev: Naukova dumka, 1992 [in Russian].

Subbotin N.B., Tomilova L.G., Kostromina N.A., Lukyanets E.A. Phthalocyanines and related compounds. XXVIII. Synthesis and spectral-electrochemical study of rare-earth monophthalocyanines. Russian J. General Chemistry. 1986. 56 (2): 397.

Subbotin N.B., Tomilova L.G., Chernykh, E.V., Kostromina N.A., Lukyanets E.A. Synthesis of unsymmetrical diphthalocyanines of rare earth elements. Russian J. General Chemistry. 1986. 56 (1): 232.

Nemykin V.N., Tsivadze A.Yu., Subbotin N.B., Kostromina N.A., Volkov S.V. Synthesis and Spectra of the Mixed-Ligand Monophthalocyanine Complexes of Rare-Earth Elements with Bidentate Oxygen-Containing Ligands. Russian Journal of Coordination Chemistry. 1996. 22 (4): 297.

Nemykin V.N., Volkov S.V. Mixed-Ligand Complexes of Lanthanides with Phthalocyanine and Its Analogues: Synthesis, Structure, and Spectroscopic Properties. Russian Journal of Coordination Chemistry. 2000. 26 (6): 436.

Nemykin V.N., Mironkzh T.I., Zub V. Ya., Volkov S.V. Chemiochromism of mixed-ligand phthalocyanine complexes of lanthanides containing phthalocyanine radical cation. Ukr. Chem. J. 1998. 64 (10): 75.

Nemykin V.N., Kostromina N.A., Subbotin N.B., Volkov S.V. // Synthesis and physico­chemical properties of highly soluble tetra-tert-butyl-2,3-naphthalocyanine complexes of lanthanides. Russian Chemical Bulletin. 1996. (1): 99.

Institute of General and Inorganic Chemistry. (Кyiv: Naukova dumka, 1993) [in Ukrainian].

Grafov A.V. Features of the establishment of metalocene complexes with tricyclic framework ligands. Ukr. Chem. J. 1997. 63 (10): 97.

Grafov A.V, Koval L.I., Traldi P., Catinella S., Battiston G. A., Zanella P. Mass-spectrometric study of some zirconocene and hafnocene dialcoholates containing a norbornane moiety. Rapid commun. Mass-Spectrom. 1996. 10: 1758 .

Grafov A.V., Traldi P., Koval L.I., Battiston G.A. Fragmentation patterns of zircono- and hafnocene dialcoholates containing menthane and bicyclo [3.1. 1] heptane moieties. Rapid commun. Mass-Spectrom. 1998. 12: 1281.

Grafov A.V., Braga F., Koval L.I., Mazurenko E.A., Battiston J.A. NMR spectra and stereochemical characteristics of complexes of zircon- and hafnocene with adamantanols. Ukr. Chem. J. 1998. 64 (7): 3.

Volkov S.V. Scientific directions and achievements in the field of physical and inorganic chemistry. Ukr. Chem. J. 2004. 70 (7): 9.

Buryak M.I., Volkov S.V. Low-temperature synthesis of metal nanoparticles and nanohe­terostructures of rhodium and from complexes in organics. Ukr. Chem. J. 2012. 78 (7): 32.

Volkov S.V. Selected notes and sketches of mo­dern chemistry. Kyіv: Publishing and Printing Center "Kyіv University", 2015.

Volkov S.V., Zheleznova L.I., Mazurenko E.A. Electronic absorption spectra of Co (II) divitonate in the gas phase. Ukr. Chem. J. 1977. 43 (3): 289.

Gerasimchuk A.I., Mazurenko E.A., Volkov S.V., Maslov V.G. Calculation of the electronic structure of β-diketonate complexes of nickel, copper and zinc by the CNDO method. Theo­retical and Experimental Chemistry. 1978. 15(2): 220.

Bublik Zh.N., Mazurenko E.A., Volkov S.V. Chromatographic method for determining the vapor pressure of coordination compounds of metals. Ukr. Chem. J. 1978. 44 (11): 1214.

Volkov S.V., Gerasimchuk A.I., Mazurenko E.A. Study of the geometric and electronic structure of pentadione-2,4, 1,1,1-trifluoropentanedione-2,4, 1,1,1,5,5,5-heskafluoropentanedione-2,4, and lithium-pentanedione-2, 4 by the method CNDO. // Russian J. Structural Chemistry. 1980. 21 (2): 168.

Mazurenko Y.A., Gerasimchuk A.I. Mechanism and kinetics of high-dispersed metals аnd oxides powders formation by use volative metal chelates. Electrochem. Soc. Proc. 1997. 97 (25): 216.

Mazurenko Y.A., Gerasimchuk A.I. Mechanism and kinetics of the formation of highly dispersed powders of metals and their oxides in CVD processes. Ukr. Chem. J. 1999. 65 (6): 83.

Gorodysky A.V., Mazurenko E.A., Nazarenko V.V., Vrochinsky S.L. Method of heat treatment of iron-carbon steels // Avt. svid. USSR №. 1453904, dated October 8, 1988.

Vrochinsky S.L., Gerasimchuk A.I., Mazurenko E.A., Medvedev A.M. Prospects for the use of chemical vapor deposition of metal coordination compounds in powder metallurgy. Collection of Metallurgy of the XXI century - the state and development strategy of Almaty. 2006. 48.

Vrochinskiy S.L., Gerasimchuk A.I., Mazurenko Є.A., Medvedev A.M., Moliar A.G. Establishment of technological pokriti in chemical precipitation from the gas phase. Physical and chemical mechanics of materials., 2006. (5): 51.

Zheleznova L., Sliusarchuk L., Rogovtsov O., Trunova E. Spectroscopis and Thermal Study of Mixed Ligand Complexes of Cobalt (II) with β-Diketones and Pyrazinamide. J.Mole­cular Crystals and Liquid Crystals. 2018. 672 (3): 123. (

Zheleznova L.I., Slyusarchuk L.I., Ivaha N.B., Kuleshov S.V., Trunova O.K. Synthesis of the synthesis of an acetylacetonate heteronuclear complex Nd (III) and Ni (II) as a precursor for the removal of folding oxide structures. Ukr. Chem. J. 2019. 85 (8): 83. (https://doi: 10.33609/0041-6045.85.8.2019.83-93).

Mazurenko E.A., Doroshenko M.N., Gerasimchuk A.I. Silicon and germanium nanotubes: synthesis, properties and modeling. Ukr. Chem. J. 2008. 74 (11): 3.

Doroshenko M.M., Zheleznova L.I., Trachevsky V.V., Mazurenko E.A. Synthesis and properties of germanium (IV) dihydroxo-bis-1,1,1,5,5,5-hexafluoro-2,4-pentanedionate – a precursor of nanostructures. Ukr. Chem. J. 2012. 78 (12): 94.

Gerasimchuk A.I. Doroschenko M.M., Mazurenko Y.A. Formation of Nanostructured Surfaces And Nanotubes By Chemical Vapor Deposition. Nanoclusters and Nanostructured Surfaces. (American Scientific Publishers, Valencia, California, USA, 2010): 449.

Doroshenko M.N., Zheleznova L.I., Mazurenko E.A. RF PE MOCVD synthesis and morphological characteristics of germanium nanoparticles. Ukr. Chem. J. 2012. 78 (8): 75.

Zheleznova L.I., Trunova O.K., Slyusarchuk L.I., Rogovtsov O.O. Method of producing volatile heterometallic hexafluoroacetyl-acetonate complexes of indium with transition me­tals. Utility model patent №119253, Ukraine, Publ. 25/09/2017, Bull. № 18.

Zheleznova L.I., Slyusarchuk L.I., Trunova E.K. Heterophase synthesis of bimetallic hexa­fluoroacetylacetonate complexes of indium with transition metals. Ukr. Chem. J. 2016. 82 (4): 69.

Berezhnitskaya A.S., Savchenko I.A., Trunova E.K., Rogovtsov A.A., Ivaha N.B.New precursors for nanomaterials on the base of a neodymium complexes. Reports of the National Academy of Sciences of Ukraine. 2012. (11): 132. (

Savchenko I., Bereznytska O., Smola S., Fedo­rov Ya., Ivaha N., Trunova E. Novel electroluminescent materials on polymer metal complexes. Functional materials. 2012. 19 (4): 551.

Efryushina N.P., Trunova E.K., Rusakova N.V., Smola S.S., Berezhnitskaya A.S., Fadeev E.N. New types of polyfunctional nanocomposite systems based on lanthanide-containing emitters. Collective monograph, ed. A.G. Naumovets Nanoscale systems and nanomaterials: research in Ukraine. Kyev: Academperiodica, 2014: 668.

Savchenko I., Berezhnytska O., Trunova O., Fedorov Ya. Monomer and metalopolymer compounds of Tb(III) as precursors for OLEDs. Applied Nanoscience. 2018. DOI 10.1007/s13204-018-0736-6.

Trunova О.К., Berezhnytska O.S., Fedorov Ya.V., Rusakova N.V., Smola S.S. Spectral-luminescent properties of Sm(III) complexes with unsaturated β-diketones. Voprosy khi­mii i khimicheskoi tekhnologii. 2019. (4): 163. (

Trunova E.K., Tananaeva N.N., Kostromina N.A., Mazurenko E.A. Binuclear citrate iron (III) complexes. Ukr. Chem. J. 1993. 59 (8): 787.

Trunova E.K., Rogovtsov A.A., Mazurenko E.A., Makotrik T.A., Shtemenko N.I. Photochemical activity of Mn (II) complexes with ethylenediaminedisuccinic acid. Ukr. Chem. J. 2001. – 67 (1): 7.

Osadchaya E.V., Trunova E.K. Mixed-ligand bimetal complexonates of copper (II) and cobalt (II). Ukr. Chem. J. 2008. 74 (3): 3.

Trunova E.K., Dudko A.V., Osadsha E.V., Shovkova A.V., Makotryk T.A. Poly [(bis((R,S)-Ethylenediamin-N,N-disuccinato)-di-cobalte(III) disodium) tetrahydrate. Acta Crystall. Section E. 2011. 67 (11): 1547.

Trunova E.K. Regularities of the complexation of 3d-metals with ethylenediaminedisuccinic acid in solutions. Ukr. Chem. J. 2013. 79 (11): 4.

Trunova O.K, Makotrik T.O, Mazurenko E.A, Rogovtsov O.O. Use of Animofer feed additive for feeding farm animals. Scientific Bulletin of NAU. 2004. (79): 140.

Shadchina T.M, Pryadkina G.O, Trunova O.K. Antichlorotic properties of trace elements of trace elements (iron and copper). Physiology and biochemistry of cultivated plants. 2008. 40, (5): 435.

Gudkov I.M, Grusha V.V, Trunova O.K Use of K2Zn(edds)∙2H2O complexate as a radioprotective compound. Utility model patent № 46569, Ukraine, Publ. 12/25/2009, Bull. № 24.

Kostromina N.A., Kryatova O.P., Trachevsky V.V., Gerasimchuk A.I. NMR research and computer modeling of the structures of hetero­nuclear boron complexes with oxyethylidene diphosphonic acid and zinc. Ukr. Chem. J. 1997. 63 (10): 90.

Kostromina N.A., Levchuk O.V., Trachevsky V.V. Heteronuclear complexes of calcium and strontium with oxyethylidene diphosphonic acid and boron. Ukr. Chem. J. 2000. 66 (7): 9.

Kostromina N.A., Kryatova O.P., Maletin Yu.A. Complex compounds of metals with boron-containing lands. Ukr. Chem. J. 2000. 66 (12): 67.

Trunova E.K., Vasin A.V., Mazurenko E.A., Melnik O.V. Synthesis and study of haloge­nated ethylenediamine-S, S'-disuccinates of pla­tinum (II). Reports of the National Academy of Sciences of Ukraine. 2004. (2): 161.

Trunova E.K., Rogovtsov A.A. Complexation in the system Ce(III)- ethylenediaminedisuccinic acid. Ukr. Chem. J. 2006. 72 (12): 74.

Trunova E.K., Fedorov Ya.V., Podgaevskaya T.P. Ca (II) complexonates based on ethylene­diaminadisuccinic acid stereoisomers. Ukr. Chem. J. 2004. 70 (9): 28.

Shovkova G.V., Trunova O.K., Gudima A.O. Synthesis and research of complex formation of a new phosphorus-containing complex with 3d metals. Ukr. Chem. J. 2010. 76 (8): 79.

Trunova O.K., Shovkova G.V, Gudima A.O., Makotrik T.O. Copper (II) complexes with bis (phosphonomethyl) aminosuccinic acid. Ukr. Chem. J. 2015. 81 (7): 38.

Gudima A.O., Shovkova G.V., Trunova O.K., Grandjean F.,Long G.J., Gerasimchuk N. Sodium-Centered Dodecanuclear Co(II) and Ni(II) Complexes with 2-(Phosphonomethylamino)succinic Acid: Studies of Spectrosco­pic, Structural, and Magnetic Properties. Inorg. Chem. 2013. 52 (13): 7467.

Trunova O.K., Rusakova N.V., Shovkova G..V, Gaidai Ya.M. Synthesis and study of heterometallic complexes of Nd (III) and Zn (II) with ethylenediaminadisuccinic acid. Ukr. Chem. J. 2014. 80 (3): 3.

Trunova E.K., Berezhnitskaya A.S., Makotrik T.A. Biheteronuclear complexes of 3-d me­tals with ethylenediaminedisuccinic acid. Ukr. Chem. J. 2017. 83 (11): 3.

Trunova O.K., Mishchenko A.M., Makotrik T.O. Synthesis and spectral characteristics of heterometallic complexes of Pr(III) with Zn(II), Co(II) based on ethylenediaminetetraacetic and ethylenediaminadisuccinic

acids. Ukr. Chem. J. 2021. 87 (3): 3.

https:// doi: 10.33609/2708-129X.87.03.2021.3-17

Trunova O.K., Shovkova G.V., Gaidai Ya.M., Rusakova N.V., Makotrik T.O., Grigorasheva I.M. Synthesis, physicochemical properties of complexes of Gd (III) and Dy (III) with ethy­lenediaminadisuccinic acid. Ukr. Chem. J. 2015. 81 (5): 22.

Pekhnyo V.I. Chalcogen chloride complexes of platinum metals (synthesis, structure, pro­perties, use). Doctoral (Chem.) Thesis (Kyiv, 1997) [in Ukrainian].

Koval L.I., Dzyuba V.I., Ilnitska O.L., Pekhnyo V.I. Efficient transesterification of ethylacetoacetate with higher alcohols without catalysts. Tetrahedron Letters. 2008. 49 (10): 1645.

doi: 10.1016/j.tetlet.2008.01018.

Koval L.I., Dzyuba V.I., Bon V.V., Ilnitska O.L., Pekhnyo V.I. Synthesis and structure of anhydrous complexes of magnesium (II) with β-ketoesters of higher alcohols // Polyhedron.– 2009. 28: 2698. doi:10.1016/j.poly.2009.05.034.

Shtokvysh O.O., Koval L.I., Pekhno V.I. Synthesis and research of cobalt (II) complexes with esters of acetoacetic acid of primary, secondary and tertiary alcohols. Ukr. Chem. J. 2015. 81 (12): 92.

Dzyuba V.I., Koval L.I., Bon V.V., Pekhnyo V.I. Synthesis and structure of lipophilic dioxo-molybdenum (VI) bis(hydroxamato) complexes. Polyhedron. 2010. 29: 2900. doi:10.1016/j.poly.2010.07.014.

Dzyuba V.I., Koval L.I., Dudko A.V., Pekhnyo V.I. N-Hydroxyhomoazaadamantanone and its complexes with dioxomolybdenum(VI) and copper(II): synthesis and structure. J. Coord. Chem. 2014. 67 (8): 1437. (

Dzyuba V.I., Koval L.I., Shtokvysh O.O., Tra­­chevskii V.V., Pekhnyo V.I. Lipophilic chloro-oxo-bis(hydroxamato)-vanadium(V) complexes: synthesis methods and structure. Polyhedron. 2020. 180: 114421.


Koval L.I., Dziuba V.I., Ilnytska O.L., Pekhno V.I., Mishchuk O.O. Coordination compounds of life metals and bioligands as model additions to environmentally friendly lubricating compositions. Him. Fiz. Tehnol. Poverhni. 2015. 6 (1): 147.

Mishchuk O.O., Koval L.I., Dzyuba V.I., Pekhno V.I. Features of bis-chelate complexes of magnesium (II), as environmentally friendly high-performance lubricating additives of new generation, in aspects of mechanochemistry of steel surface. Reports of the National Academy of Sciences of Ukraine. 2020. (6): 83. (

Tsarik N.V., Kozachkova A.N., Kostromina N.A., Pehnyo V.I. Determination of the composition and constants of formation of palladium complexes with oxyethylidenediphosphonic acid. Ukr. Chem. J. 2006. 72 (1): 19.

Kozachkova A.N., Tsarik N.V., Kostromina N.A., Pehnyo V.I. Interaction of cis-diamine dichloropalladium (II) with oxyethylidenediphosphonic acid. Ukr. Chem. J. 2007. 73 (3): 15.

Tsarik N.V., Kozachkova A.N., Trachevsky V.V., Rozhenko A.B., Pekhnio V.I. Palladium (II) complexes with 1-hydroxyethylidene-1,1-diphosphonic acid. Russian J. Coordination Chemistry. 2008. 34 (7): 500.

Kozachkova A.N., Tsarik N.V., Pekhnio V.I., Tolstorozhev G.B., Skornyakov. I.V. Complexa­tion of palladium (II) with methylene diphosphonic acid. Ukr. Chem. J. 2012. 78 (3): 15.

Kozachkova A.N., Dudko A.V., Tsarik N.V., Trachevsky V.V., Rozhenko A.B., Pekhnio V.I. Interaction of K2PdCl4 with aminoalkyl diphosphonic acids. Russian Journal of Inorganic Chemistry. 2011. 56 (9): 1571.

Kozachkova A.N., Dudko A.V., Tsarik N.V., Trachevsky V.V., Rozhenko A.B., Pekhnio V.I. Various methods of coordination of aminoalkyldiphosphonic acids in complexes with palladium (II). Russian J. Coordination Che­mistry. 2011. 37 (12): 943.

Kozachkova A.N., Tsarik N.V., Trachevsky V.V., Lavrik R.V., Pekhnio V.I. Complexation of dichloro (ethylenediamine) palladium (II) with methylene diphosphonic acid. Ukr. Chem. J. 2018. 84 (9): 3.

Kozachkova O.M., Tsaryk N.V., Pekhnyo V.I., Trachevskyi V.V., Rozhenko A.B., Dyakonenko V.V. Complexation of dichloro (ethylenediamine) palladium (II) with 1-hydroxyethy­lidene-1,1-diphosphonic acid. Inorganica Chimica Acta. 2018. 474: 96.

Dudko A.V., Tsarik N.V., Kozachkova A.N., Pekhnio V.I. Interaction of palladium (II) with 1-aminoethylidene diphosphonic acid. Ukr. Chem. J. 2008. 72 (7): 12.

Pekhno V.I., Kozachkova O.M., Tsarik N.V., Kutsenko I.P., Trachevsky V.V., Sharikina N.I, Tolstorozhev G.B. Features of complexation of palladium (II) with bisphosphonic acids. Ukr. Chem. J. 2014. 80 (7–8): 23.

Dudko A.V., Bon V.V., Kozachkova A.N., Tsarik N.V., Pekhnyo V.I. Synthesis and structure of 1-aminoethylidenediphosphonic acid. Ukr. Chem. J. 2008. 72 (10): 104.

Bon V.V., Dudko A.V. Kozachkova A.N., Pekhnyo V.I. Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrate. Acta Cryst. 2008. E64: 2344.

Dudko A.V., Bon V.V., Kozachkova A.N., Tsaryk N.V., Pekhnyo V.I. Oxonium (dihydrogen 1-aminoethane-1,1-diyldiphosphonato-2N,O)[hydrogen (1-amino-1-phosphonoethyl)phosphonato-2N,O]palladium(II) trihydrate. Acta Cryst. 2010. E66: 170.

Babaryk A.A., Kozachkova A.N., Tsaryk N.V., Dudko A.V., Pekhnyo V.I. Binary salt of Pd(II) complex with (phosphonomethyl)phosphonic (medronic) acid comprising ''handbell''-like [Pd([mu]-CH2(PO3)2]3 units. Acta Cryst. 2012. С68: 242.

Kutsenko I.P., Kozachkova A.N.,. Tsaryk N.V, Pekhnyo V.I.,. Rusanova J.A. Poly[[tri-1-aqua-­dodecaaquatris(μ3-1-hydroxyethylidene-1,1-diphosphonato)tricalcium(II)tripalla-dium(II)] pentahydrate]. Acta Cryst. 2014. E70: 291.

Pekhnyo V.I., Kozachkova A.N., Tsarik N.V., Kutsenko I.P., Sharykina N.I., Grigorieva T.I., Lukyanova N.Yu., Todor I.N., Chekhun V.F. Antineoplastic, low-toxic, targeted delivery, broad-spectrum, nanosized palladium (II) phosphonates are potential medicinal substances. Collective monograph, ed. A.G. Naumovets Nanoscale systems and nanomaterials: research in Ukraine. Kyiv: Academperiodica, 2014: 486.

Tolstorozhev G.B., Belkov M.V., Skornyakov I.V., Pekhnio V.I., Kozachkova A.N., Tsarik N.V., Kutsenko I.P., Sharykina N.I. Methods of infrared spectroscopy in the control of chemotherapy oncological pathologists with palladium complexes. Optics and Spectroscopy. 2014. 17 (5): 876.

Rybachuk L.M. Synthesis, properties, structure of coordination compounds of Ru (III) with hydrazones of salicylic aldehyde: PhD (Chem.) Thesis (Kyiv, 20057). [in Ukrainian]. 140. Bon V.V. Synthesis, structure, properties of coordination compounds of Rh (III) and Pd (II) with aromatic derivatives of salicylaldimines and carbothioamides: PhD (Chem.) Thesis (Kyiv, 2007) [in Ukrainian].

Ghоlоb О.О. Coordination compounds of transition metals with derivatives of hydroxyiminoacetic acid and carbotioamides. Synthesis, structure, bioactivity, analytical forms: PhD (Chem.) Thesis (Kyiv, 2015) [in Ukrainian].

Repich G.G. Synthesis, structure and spectral characteristics of complexes of Fe (III), Co (II), Ni (II), Cu (II), Pd (II), Pt (II), Ag (I) with derivatives of thiourea, hydrazones and thiosemicarbazones : PhD (Chem.) Thesis (Kyiv, 2016) [in Ukrainian].

Borovik P.V. Synthesis, structure and properties of coordination compounds Ru(III), Rh(III), Pd(II), Pt(II) and Ag(I) with N-allyl-substituted carbothioamides: PhD (Chem.) Thesis (Kyiv, 2021) [in Ukrainian].

Orysyk S.I., Bon V.V., Zholob O.O., Pekhnyo V.I., Orysyk V.V., Zborovskii Yu.L., Vovk M.V. Novel Pd(II) coordination compounds involving 2-[(2-Hydroxyphenyl)methylene]hydrazine-N-(2-propenyl)-carbothioamide as a ligand or proligand: Synthesis, crystal structures and analytical application. Polyhedron. 2013. 51: 211.

Orysyk S.I., Bon V.V., Obolentseva O.V., Zbo­rovski Yu.L.i, Orysyk V.V., Pekhnyo V.I., Staninets V.I., Vovk V.M. Synthesis, structural and spectral characterization of Zn(II) complexes, derived from thiourea and thiosemicarbazide. Inorganica Chimica Acta. 2012. 382: 127.

Orysyk S.I., Bon V.V., Pekhnyo V.I., Zbo­rov­skii Yu.L., Orysyk V.V., Vovk M.V. Synthesis, structure and spectral characteristics of Ni(II), Pd(II) and Zn(II) complexes with N-(2-pyri­dinyl)morpholine-4-carbothioamide. Polyhedron. 2012. 38: 15.

Orysyk S.I., Repich G.G., Bon V.V., Dyakonenko V.V., Orysyk V.V.,. Zborovskii Yu.L, Shishkin O.V., Pekhnyo V.I., Vovk M.V. Novel Fe(III), Co(III), Ni(II), Cu(II) coordination compounds involving 2-[(2-hydroxyphenyl)me­thy­lene]hydrazine-N-(2-propenyl)-carbothioamide as ligand: Synthesis, crystal structures and spectral characteristics. Inorganica Chimica Acta. 2014. 423: 496.

Orysyk S.I., Zholob O.O., Bon V.V., Nikulina V.V., Orysyk V.V., Nikolaienko T.V., Garmanchuk L.V., Zborovskii Yu.L., Tolstanova G.M., Khranovskaya N.N., Pekhnyo V.I., Vovk M.V. Novel chelate complexes of Co(II), Ni(II), Cu(II), Pd(II) derived from anti- and syn-isomers of 2-(2-aminothiazole-4-yl)-2-hydroxyiminoacetic acid with pro-/antiproliferative actions on endothelial cells. Polyhedron. 2015. 85: 208.

Repich H.H., Orysyk V.V., Palchykovska L.G., Orysyk S.I., Zborovskii Yu.L., Vasylchenko O.V., Storozhuk O.S., Biluk A.A., Nikulina V.V., Garmanchuk L.V., Pekhnyo V.I., Vovk M.V. Synthesis, spectral characterization of novel Pd(II), Pt(II) π-coordination compounds based on N-allylthioureas. Cytotoxic properties and DNA binding ability. J. Inorganic Biochemistry. 2017 168: 98.

Orysyk S.I., Borovyk P.V., Repich H.H., Severynovska O.V., Zborovskii Yu. L., Mishchenko A.M., Orysyk V.V., Pekhnyo V.I., Vovk M.V. Synthesis, spectral characterization and DFT calculations of novel Ag (I) π-coordination polymeric complexes based on N-allylmorpholine-4-carbothioamide. J. Molecular Structure. 2020. 1208: 127866.

Borovyk P.V., Orysyk S.I., Repich H.H., Likhanov A.F., Mishchenko A.M., Zborovskii Yu.L., Orysyk V.V., Palchikovska L.G., Pekhnyo V.I., Vovk M.V. Spectral characteristics andcytostatic effect of Pd(II) and Pt(II) carbothioamide π-complexes on Allium Cepa L Meristem cells. Voprosy khimii i khimicheskoi tekhnologii. 2020. (3): 34.

Borovik P.V., Litvinchuk M.B., Bentya A.V., Orysyk S.I., Zborovsky Y.L., Orysyk V.V., Pekhno V.I., Vovk M.V. Synthesis and spectral characteristics of complexes of Ru (III, II), Rh (III) and Pd (II) with N-allylthioamides and products of their proton and iodocyclization. Ukr. Chem. J. 2020. 86 (4): 63.


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