PROBLEMS OF DEVELOPMENT OF THE METHOD OF X-RAY PHOTOELECTRON SPECTROSCOPY IN UKRAINE
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Keywords

X-ray photoelectron spectroscopy, XPS, ESCA, energy analyzer, spectro­meter.

How to Cite

Korduban, O., Ogenko, V., & Kryshchuk, T. (2021). PROBLEMS OF DEVELOPMENT OF THE METHOD OF X-RAY PHOTOELECTRON SPECTROSCOPY IN UKRAINE. Ukrainian Chemistry Journal, 87(1), 41-50. https://doi.org/10.33609/2708-129X.87.01.2021.41-50

Abstract

The article is devoted to the development problems of the X-ray Photoelectron Spectroscopy (XPS) method in Ukraine. XPS is a modern method for studying the electronic structure of atoms. The XPS method is used at all stages of the synthesis and study of materials, the functional properties of which are determined by the state of the surface or interphase boundaries, charge states of atoms and the type of functional groups, and material degradation processes. The objects of study are catalysts, coatings, chemical sensors, sorbents, coordination and organometallic compounds (chemistry, materials science, phar­maceuticals), surface condition and composition (microelectronics), thin films (optics), alloys (aviation and space industry), nanopowders, nanofilms (nanotechnology). The method is relevant for the implementation of targeted synthesis of materials. In the world, the XPS method is widespread and integrated into innovative branches of science and technology, and XPS - instrumentation - is a high-tech business. In Ukraine, the method is practically not presented, there is no competition in this field of instrumentation. The article proposes the creation on the basis of the National Academy of Sciences of Ukraine a park of unitary, high-quality and affordable domestic XPS-spectrometers and the opening of a service center. The XPS method is necessary for most of the institutes of the National Academy of Sciences of Ukraine from the departments of chemistry, physics and astronomy, physical and technical problems of materials science, earth sciences and all specialized faculties of state universities. In general, for Ukraine, this is at least 50 spectrometers. The mechanism for the implementation of the project can be the formation of a state order for the development and manufacture of a batch of XPS spectrometers on the basis of imported and domestic components (50:50) and attracting business to the project. Creation of a network of Domestic XPS-spectrometers allows to obtain a sharp increase in the efficiency of scientific research in chemistry, physics, materials science and is one of the conditions for Ukraine’s transition to an innovative economy.

https://doi.org/10.33609/2708-129X.87.01.2021.41-50
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References

1. Siegbahn, K. ESCA: atomic, molecular and solid state structure studies by means of electron spectroscopy; pres. to the Royal Society of Sciences of Uppsala, Dec. 3rd, 1965. Nova Acta Regiae Societatis Scientiarum Upsaliensis. 1967.
2. Nefedov V. Y. Renthenoэlektronnaia spekt­ro­skopyia khymycheskykh soedynenyi. Moskva, Khymyia. 1984.
3. Briggs D., Seach M. P.. Practical Surface Analysis by Auger and X-ray Photoelectron Spectroscopy. Chichester - New York, John Wiley & Sons Ltd. 1983.
4. Wagner C.D., Moulder J.F., Davis L.E., Riggs W.M.. Handbook of X-ray Photoelectron Spectroscopy. New York, Perkin-Elmer Corporation. 1979.
5. World X-ray Photoelectron Spectroscopy (XPS) Market Research Report 2022
https://www.egypt-business.com/Ticker/
details/1805-World-X-ray-Photoelectron-
Spectroscopy-XPS-Market-Research-Report-2022/212473
6. X-Ray Photoelectron Spectroscopy Market Analysis & Trends to 2025: Kratos Analy­tical, Thermo Fisher Scientific, ULVAC and Other http://www.digitaljournal.com/pr/4157778
7. X-Ray Photoelectron Spectroscopy(XPS) Market: Rising Medical and Pharmaceutical Applications to Bolster Growth Prospects
https://www.prnewswire.com/news-releases/x-ray-photoelectron-spectroscopy-xps-market-rising-medical-and-pharmaceutical-applications-to-bolster- growth-prospects-619818163.html
8. Sulim I. Y., Borysenko M. V., Kordu­ban O. M.,Gun’ko V. M. Influence of silica matrix morphology on characteristics of grafted nanozirconia. Applied Surface Science. 2009. 255 (17):7818.
9. Caricato A. P., Luches A., Martino M., Va­le­rini D., Kudryavtsev Y. V., Korduban A. M., Mulenko S. A., Gorbachuk N. T. Deposition of chromium oxide thin films with large thermoelectromotive force coefficient by reactive pulsed laser ablation. Journal of Optoelectronics and Advanced Materials. 2010. 12(3):427.
10. Caricato A.P., Gorbachuk N.T., Kordu­ban A.M., Leggieri G., Luches A., Mengucci P., Mulenko S.A., Valerini D.. Structural, electrical, and optical characterizations of laser deposited nanometric iron oxide films. Journal of Vacuum Science and Technology. 2010. 28(2):295.
11. Yashchishyn I.A., Korduban A.M., Konstantinova T.E., Danilenko I.A., Volkova G.K., Glazunova V.A., Kandyba V.O. Structure and surface characterization of ZrO2-Y2O3-Cr2O3 system. Applied Surface Science. 2010. 256(23):7175.
12. Yashchishyn I.A., Trachevsky V.V., Korduban A.M., Konstantinova T.E., Danilenko I.A., Volkova G.K., Nosolev I.K.. State Peculiarities of Hydrate Shell on the Surface of Nanoparticles of ZrO2-Y2O3 under Cr Doping. Physics and Chemistry of Solid State. 2010. 11(1):181.
13. Gun’ko V.M., Bogatyrev V.M., Borysenko M.V., Galaburda M.V., Sulim I.Y., Petrus L.V., Korduban O.M., Polshin E.V., Zaulychnyy Ya.V.. Morphological, structural and adsorption features of oxide composites with silica and titania matrices. Applied Surface Science. 2010. 256(17):5263.
14. Socol G., Gnatyuk Yu., Stefan N., Smirnova N., Korduban O., Djokić V., Sutan C.. Photocatalytic activity of pulsed laser deposited TiO2 thin films in N2, O2 and CH4. Thin Solid Films. 2010. 518(16), 4648.
15. Gnatyuk, Y., Smirnova, N., Korduban, O., & Eremenko, A. Effect of zirconium incorporation on the stabilization of TiO2 mesoporous structure. Surface and Interface Analysis. 2010. 42(6‐7):1276.
16. Yashchishyn I.A., Korduban A.M., Trachevsky V.V., Konstantinova T.E., Danilenko I.A., Volkova G.K., Nosolev I.K.. XPS and ESP spectroscopy of ZrO2-Y2O3 – Cr2O3 nanopowders. Functional Materials. 2010. 17(3): 306.
17. Eremenko A., Smirnova N., Gnatiuk Yu., Linnik O., Vityuk N., Mukha Yu., Korduban A.. Silver and gold nanoparticles on sol-gel TiO2, ZrO2, SiO2 surfaces: optical spectra, photocatalytic activity, bactericide properties. Nanocomposites and Polymers with Analytical Methods. 2011. 3:52.
18. Krasnyakova T.V., Zhikharev I.V., Mitchenko R.S., Burkhovetski V.I., Korduban A.M., Kryshchuk T.V., Mitchenko S.A.. Acetylene catalytic hydrochlorination over mechanically pre-activated K2PdCl4 salt: A study of the reaction mechanism. Journal of Catalysis. 2012. 288: 33.
19. Linnik O., Petrik I., Smirnova N., Kandyba V., Korduban O., Eremenko A., Socol G., Stefan N., Ristoscu C., Mihailescu I.N., Ssutan C., Malinovschi V., Djokic V., Jana­kovic D.. TiO2/ZrO2 thin films synthesized by PLD in low pressure N-, C- and/or O-containing gases: structural, optical and photocatalytic properties. Journal of Nanomaterials and Biostructures. 2012. 7(3):1343.
20. Linnik O., Smirnova N., Korduban O., Ere­menko A.. Gold nanoparticles into Ti1-xZnxO2 Films: synthesis, structure and application. Materials Chemistry and Physics. 2013. 142(1):318.
21. Bykov I.P., Zagorodniy Y.A., Yurchenko L.P., Korduban A.M., Nejezchleb K., Trachevsky V. V., Dimza V., Jastrabik L., Dejneka A.. Using the Methods of Radiospectroscopy (EPR, NMR) to Study the Nature of the Defect Structure of Solid Solutions Based on Lead Zirconate Tita­nate (PZT). IEEE transactions on ultrasonics, ferroelectrics, and frequency control. 2014. 61(8):1379.
22. Pirskyy Yu., Murafa N., Korduban O.M., Subrt J.. Nanostructured catalysts for oxy­gen electroreduction based on bimetallic monoethanolamine complexes of Co(III) and Ni(II). Journal of Applied Electroche­mistry. 2014. 44(11):1193.
23. Linnik O., Shestopal N., Smirnova N., Eremenko A., Korduban O., Kandyba V., Kryshchuk T., Socol G., Stefan N., Popescu-Pelin G., Ristoscu C., Mihailescu I.N.. Correlation between electronic structure and photocatalytic properties of non-metal doped TiO2/ZrO2 thin films obtained by pulsed laser deposition method. Vacuum. 2015. 114:166.
24. Pylypchuk I.V., Petranovskaya A.L., Gorbyk P. P., Korduban A. M., Markovsky P. E., Ivasishin O.M.. Biomimetic Hydroxyapatite Growth on Functionalized Surfaces of Ti-6Al-4V and Ti-Zr-Nb Alloys. Nanoscale Research Letters. 2015. 10(1):1.
25. Inshina O., Korduban A., Tel’biz G., Brei V.. Synthesis and study of superacid ZrO2–SiO2–Al2O3 mixed oxide. Adsorption Science & Technology. 2017. 35(5-6): 439.
26. Pylypchuk I.V., Gorbyk P.P., Petranov­ska A.L., Korduban O.M., Markovsky P.E. Formation of biomimetic hydroxyapatite coatings on the surface of titanium and Ti-containing alloys: Ti–6Al–4V and Ti–Zr–Nb. Surface Chemistry of Nanobiomaterials. 2016. 193.
27. Linnik O., Chorna N., Smirnova N., Eremenko A., Korduban O., Stefan N., Ristoscu C., Socol G., Miroiu M., Mihailescu I. Pulsed Laser-Deposited TiO2-based Films: Synthesis, Electronic Structure and Photo­catalytic Activity. Semiconductor Photocatalysis: Materials, Mechanisms and Applications. 2016. 135.
28. Galaguz V., Korduban O., Panov E., Malo­vanyi S. The use of Raman and XPS spectroscopy to study the cathode material of LiFePO4/C. Journal of the Serbian Chemical Society. 2020. 0:11.

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